| 0 | 1‐Azaspiro[3.3]heptane as a Bioisostere of Piperidine** | ACIE |
| 1 | A General Light‐Driven Organocatalytic Platform for the Activation of Inert Substrates | ACIE |
| 2 | A Homo‐Mannich Reaction Strategy Enables Collective Access to Ibophyllidine, Aspidosperma, Kopsia, and Melodinus Alkaloids | ACIE |
| 3 | A Photochemical Strategy for ortho‐Aminophenol Synthesis via Dearomative‐Rearomative Coupling Between Aryl Azides and Alcohols | ACIE |
| 4 | A Traceless Chiral Shift Reagent Based on Nonbonding Interactions with Single‐Handed Helical Poly(quinoxaline‐2,3‐diyl) | ACIE |
| 5 | Accelerated Electrophotocatalytic C(sp3)−H Heteroarylation Enabled by an Efficient Continuous‐Flow Reactor** | ACIE |
| 6 | Air‐Stable Organoradical Boron Reagents | ACIE |
| 7 | Ammonia Synthesis at Room Temperature and Atmospheric Pressure from N2: A Boron‐Radical Approach | ACIE |
| 8 | An Iridium/Aluminum Cooperative Strategy for the β‐C(sp3)‐H Borylation of Saturated Cyclic Amines | ACIE |
| 9 | Asymmetric Synthesis of Vicinal Tetrasubstituted Diamines via Reductive Coupling of Ketimines Templated by Chiral Diborons | ACIE |
| 10 | Asymmetric Total Synthesis of Hasubanan Alkaloids: Periglaucines A–C, N,O‐Dimethyloxostephine and Oxostephabenine | ACIE |
| 11 | Bifunctional Iminophosphorane‐Catalyzed Enantioselective Nitroalkane Addition to Unactivated α,β‐Unsaturated Esters** | ACIE |
| 12 | Bismuth‐Catalyzed Amide Reduction | ACIE |
| 13 | Brønsted Acid Catalysis—Controlling the Competition between Monomeric versus Dimeric Reaction Pathways Enhances Stereoselectivities | ACIE |
| 14 | Carbene‐Catalyzed Intermolecular Dehydrogenative Coupling of Aldehydes with C(sp3)−H Bonds | ACIE |
| 15 | Catalytic Asymmetric Conjugate Reduction | ACIE |
| 16 | Catalytic Photochemical Deracemization via Short‐Lived Intermediates | ACIE |
| 17 | Catalytic Photoinduced Intramolecular Decarboxylative and Desulfonylative sp3 Allylation Enabled by Sulfinate Salts | ACIE |
| 18 | Catalytic SNAr Hexafluoroisopropoxylation of Aryl Chlorides and Bromides | ACIE |
| 19 | Catalytic σ‐Bond Annulation with Ambiphilic Organohalides Enabled by β‐X Elimination** | ACIE |
| 20 | Catalytic, Regioselective 1,4‐Fluorodifunctionalization of Dienes | ACIE |
| 21 | Cationic Rhodium(I) Tetrafluoroborate Catalyzed Intramolecular Carbofluorination of Alkenes via Acyl Fluoride C−F Bond Activation** | ACIE |
| 22 | Chiral Iron Porphyrins Catalyze Enantioselective Intramolecular C(sp3)−H Bond Amination Upon Visible‐Light Irradiation | ACIE |
| 23 | Close‐Shell Reductive Elimination versus Open‐Shell Radical Coupling for Site‐Selective Ruthenium‐Catalyzed C−H Activations by Computation and Experiments | ACIE |
| 24 | Cobalt‐Catalyzed Enantioselective Hydroamination of Arylalkenes with Secondary Amines | ACIE |
| 25 | Cobalt‐Catalyzed Wagner–Meerwein Rearrangements with Concomitant Nucleophilic Hydrofluorination | ACIE |
| 26 | Construction of Chiral Quaternary Carbon Centers via Asymmetric Metal Carbene gem‐Dialkylation | ACIE |
| 27 | Copper‐Catalyzed Enantioconvergent Radical C(sp3)−N Cross‐Coupling: Access to α,α‐Disubstituted Amino Acids | ACIE |
| 28 | Copper‐Catalyzed Oxygenative Skeletal Rearrangement of Tetrahydro‐β‐carbolines Using H2O and O2 as Oxygen Sources | ACIE |
| 29 | Csp3−PIII Bond Formation via Cross‐Coupling of Umpolung Carbonyls with Phosphine Halides Catalyzed by Nickel | ACIE |
| 30 | Cu‐Catalyzed Asymmetric Kinetic Boron Conjugate Addition of γ‐Substituted α,β‐Unsaturated γ‐Lactams | ACIE |
| 31 | C−H Activation of Unbiased C(sp3)−H Bonds: Gold(I)‐Catalyzed Cycloisomerization of 1‐Bromoalkynes** | ACIE |
| 32 | Dearomatization‐Rearomatization Reaction of Metal‐Polarized Aza‐ortho‐Quinone Methides | ACIE |
| 33 | Design of Furan‐Based Acceptors for Organic Photovoltaics | ACIE |
| 34 | Diastereoselective Alkylation of Activated Nitrogen Heterocycles with Alkenyl Boronate Complexes | ACIE |
| 35 | Diastereoselective Synthesis of Cyclopropanes from Carbon Pronucleophiles and Alkenes | ACIE |
| 36 | Diastereoselective Synthesis of Monofluorocyclohexenes through Photocatalyzed Cascade Cyclization of gem‐Difluoroalkenes and α,β‐Unsaturated Carbonyl Compounds | ACIE |
| 37 | Diazoalkenes: From an Elusive Intermediate to a Stable Substance Class in Organic Chemistry | ACIE |
| 38 | Direct Light‐Enabled Access to α‐Boryl Radicals: Application in the Stereodivergent Synthesis of Allyl Boronic Esters** | ACIE |
| 39 | Discrimination of the Enantiotopic Faces of Structurally Unbiased Carbenium Ions Employing a Cyclohexadiene‐Based Chiral Hydride Source | ACIE |
| 40 | Divergent Synthesis of Alcohols and Ketones via Cross‐Coupling of Secondary Alcohols under Manganese Catalysis | ACIE |
| 41 | Donor‐Acceptor Aminocyclobutane Monoesters: Synthesis and Silylium‐Catalyzed (4+2) Annulation with Indoles | ACIE |
| 42 | Dual Photochemical H‐Atom Transfer and Cobalt Catalysis for the Desaturative Synthesis of Phenols from Cyclohexanones | ACIE |
| 43 | Economical Access to Diverse Enantiopure Tetrahydropyridines and Piperidines Enabled by Catalytic Borrowing Hydrogen | ACIE |
| 44 | Electrochemical NiH‐Catalyzed C(sp3)−C(sp3) Coupling of Alkyl Halides and Alkyl Alkenes | ACIE |
| 45 | Enantioselective Hydroalkenylation and Hydroalkynylation of Alkenes Enabled by a Transient Directing Group: Catalyst Generality through Rigidification** | ACIE |
| 46 | Enantio‐ and Diastereoselective NiH‐Catalyzed Hydroalkylation of Enamides or Enecarbamates with Racemic α‐Bromoamides** | ACIE |
| 47 | Ethene‐1,1‐disulfonyl Difluoride (EDSF) for SuFEx Click Chemistry: Synthesis of SuFExable 1,1‐Bissulfonylfluoride Substituted Cyclobutene Hubs | ACIE |
| 48 | Experimental and Computational Studies on Cobalt(I)‐Catalyzed Regioselective Allylic Alkylation Reactions | ACIE |
| 49 | Formal γ−C−H Functionalization of Cyclobutyl Ketones: Synthesis of cis‐1,3‐Difunctionalized Cyclobutanes | ACIE |
| 50 | Free Amino Group Transfer via α‐Amination of Native Carbonyls | ACIE |
| 51 | General Synthesis of 3‐Azabicyclo[3.1.1]heptanes and Evaluation of Their Properties as Saturated Isosteres** | ACIE |
| 52 | Geometric Isomerisation of Bifunctional Alkenyl Fluoride Linchpins: Stereodivergence in Amide and Polyene Bioisostere Synthesis | ACIE |
| 53 | Gold‐Catalyzed Amine Cascade Addition to Diyne‐Ene: Enantioselective Synthesis of 1,2‐Dihydropyridines | ACIE |
| 54 | Hydrogen‐Atom‐Transfer‐Initiated Radical/Polar Crossover Annulation Cascade for Expedient Access to Complex Tetralins | ACIE |
| 55 | Imine Directed Cp*RhIII‐Catalyzed N−H Functionalization and Annulation with Amino Amides, Aldehydes, and Diazo Compounds | ACIE |
| 56 | In Situ Quench Reactions of Enantioenriched Secondary Alkyllithium Reagents in Batch and Continuous Flow Using an I/Li‐Exchange | ACIE |
| 57 | Intramolecular Ynamide–Benzyne (3+2) Cycloadditions | ACIE |
| 58 | Late‐Stage Formal Double C−H Oxidation of Prenylated Molecules to Alkylidene Oxetanes and Azetidines by Strain‐Enabled Cross‐Metathesis | ACIE |
| 59 | Late‐Stage Halogenation of Peptides, Drugs and (Hetero)aromatic Compounds with a Nucleophilic Hydrazide Catalyst | ACIE |
| 60 | Manganese(I) Catalyzed ortho C−H Allylation of Benzoic Acids | ACIE |
| 61 | Manganese‐Catalyzed Redox‐Neutral Thiolation of Alkyl Halides with Thioformates | ACIE |
| 62 | Mesoionic Carbene‐Catalyzed Formyl Alkylation of Aldehydes | ACIE |
| 63 | Metal Free Dötz‐Type Aminobenzannulation Reaction via 1,1‐Dipoles Cross‐Coupling | ACIE |
| 64 | Metallaphotoredox‐Catalyzed Enantioselective Cross‐Electrophile Coupling Using Alcohols as Reducing Agents | ACIE |
| 65 | Metal‐Free Arylation of Benzothiophenes at C4 by Activation as their Benzothiophene S‐Oxides | ACIE |
| 66 | Nickel‐Catalyzed Chemoselective Arylation of Amino Alcohols | ACIE |
| 67 | Nickel‐Catalyzed Kinetic Resolution of Racemic Unactivated Alkenes via Enantio‐, Diastereo‐, and Regioselective Hydroamination | ACIE |
| 68 | Nickel‐Catalyzed Tunable Enantioconvergence and Kinetic Resolution in the Coupling of Tertiary Cyclobutenols with Arylboroxines | ACIE |
| 69 | Non‐native Intramolecular Radical Cyclization Catalyzed by a B12‐Dependent Enzyme** | ACIE |
| 70 | Olefin Dihydroxylation Using Nitroarenes as Photoresponsive Oxidants | ACIE |
| 71 | Organocatalytic Enantioselective Vinylcyclopropane‐Cyclopentene (VCP‐CP) Rearrangement | ACIE |
| 72 | Orthogonal Olefination with Organogermanes | ACIE |
| 73 | Oxidation and Reduction Pathways in the Knowles Hydroamination via a Photoredox‐Catalyzed Radical Reaction** | ACIE |
| 74 | Palladium/Norbornene‐Catalyzed Direct Vicinal Di‐Carbo‐Functionalization of Indoles: Reaction Development and Mechanistic Study | ACIE |
| 75 | Palladium‐Catalyzed Benzylic C(sp3)−H Carbonylative Arylation with Aryl Bromides | ACIE |
| 76 | Palladium‐Catalyzed Branch‐ and Z‐Selective Allylic C−H Amination with Aromatic Amines | ACIE |
| 77 | Palladium‐Catalyzed Carbonylative Difunctionalization of Unactivated Alkenes Initiated by Unstabilized Enolates | ACIE |
| 78 | Palladium‐Catalyzed Enantio‐ and Regioselective Ring‐Opening Hydrophosphinylation of Methylenecyclopropanes | ACIE |
| 79 | Peptide Cyclization by the Use of Acylammonium Species | ACIE |
| 80 | Phosphoric Acid‐Catalyzed Enantioselective Synthesis of Axially Chiral Anthrone‐based Compounds | ACIE |
| 81 | Photocatalytic Alkylation of C(sp3)−H Bonds Using Sulfonylhydrazones** | ACIE |
| 82 | Photocatalytic C−C Cleavage of Methylenecyclobutanes for γ,δ‐Unsaturated Aldehydes by Strain Release | ACIE |
| 83 | Photochemical Deracemization of 3‐Substituted Oxindoles | ACIE |
| 84 | Photoredox Catalysis for the Synthesis of N‐CF2H Compounds Using 1‐((N‐(difluoromethyl)‐4‐methylphenyl)‐sulfonamido)pyridin‐1‐ium Trifluoromethanesulfonate | ACIE |
| 85 | Photosensitized [4+2]‐ and [2+2]‐Cycloaddition Reactions of N‐Sulfonylimines | ACIE |
| 86 | Regiodivergent C−H Acylation of Arenes by Switching from Ionic‐ to Radical‐Type Chemistry Using NHC Catalysis | ACIE |
| 87 | Regio‐ and Stereoselective Hydroelementation of SF5‐Alkynes and Further Functionalizations. | ACIE |
| 88 | Room‐Temperature‐Stable Diazoalkenes by Diazo Transfer from Azides: Pyridine‐Derived Diazoalkenes | ACIE |
| 89 | Stiba‐, Arsa‐ and Phosphastannenes: Syntheses and Reactivities | ACIE |
| 90 | Sulfonium Salts as Acceptors in Electron Donor‐Acceptor Complexes | ACIE |
| 91 | Synthesis of 2‐Azanorbornanes via Strain‐Release Formal Cycloadditions Initiated by Energy Transfer | ACIE |
| 92 | Synthesis of a Systematic 64‐Membered Heparan Sulfate Tetrasaccharide Library | ACIE |
| 93 | Synthesis of α‐Branched Enones via Chloroacylation of Terminal Alkenes | ACIE |
| 94 | The Construction of Highly Substituted Piperidines via Dearomative Functionalization Reaction | ACIE |
| 95 | The Indenyl Effect: Accelerated C−H Amidation of Arenes via Ind*RhIII Nitrene Transfer Catalysis** | ACIE |
| 96 | Traffic Lights for Catalysis: Stimuli‐Responsive Molecular and Extended Catalytic Systems | ACIE |
| 97 | Translating Planar Heterocycles into Three‐Dimensional Analogs by Photoinduced Hydrocarboxylation** | ACIE |
| 98 | Trifluoromethylation of Carbonyl and Unactivated Olefin Derivatives by C(sp3)−C Bond Cleavage | ACIE |
| 99 | Triflylpyridinium Enables Rapid and Scalable Controlled Reduction of Carboxylic Acids to Aldehydes using Pinacolborane | ACIE |
| 100 | Trinuclear Gold‐Catalyzed 1,2‐Difunctionalization of Alkenes | ACIE |
| 101 | Unlocking Migratory Insertion in Gold Redox Catalysis | ACIE |
| 102 | Visible Light‐Mediated Cyclisation Reaction for the Synthesis of Highly‐Substituted Tetrahydroquinolines and Quinolines | ACIE |
| 103 | [2+2+1+1] Cycloaddition for de novo Synthesis of Densely Functionalized Phenols | ACIE |
| 104 | β‐Arylation of Racemic Secondary Benzylic Alcohols to Access Enantioenriched β‐Arylated Alcohols | ACIE |
| 105 | Asymmetric Formal Abnormal Claisen Rearrangement Enabled by Rh-Catalyzed Regio- and Enantioselective Allylic Alkylation | ACS Catalysis |
| 106 | Cooperative Asymmetric Dual Catalysis Involving a Chiral N-Heterocyclic Carbene Organocatalyst and Palladium in an Annulation Reaction: Mechanism and Origin of Stereoselectivity | ACS Catalysis |
| 107 | Copper-Catalyzed Enantioselective Borylative Allyl–Allyl Coupling of Allenes and Allylic gem-Dichlorides | ACS Catalysis |
| 108 | Four-Component Synthesis of Spiro-Imidazolidines Enabled by Carbon Nitride Photocatalysis | ACS Catalysis |
| 109 | Mechanistic Investigation on Dearomative Spirocyclization of Arenes with α-Diazoamide under Boron Catalysis | ACS Catalysis |
| 110 | Nickel-Catalyzed 1,1-Aminoborylation of Unactivated Terminal Alkenes | ACS Catalysis |
| 111 | Organocatalytic Deoxyhalogenation of Alcohols with Inorganic Halides | ACS Catalysis |
| 112 | Photocatalytic Hydrogen Atom Transfer-Induced Arbuzov-Type α-C(sp3)–H Phosphonylation of Aliphatic Amines | ACS Catalysis |
| 113 | The Merger of Aryl Radical-Mediated Halogen-Atom Transfer (XAT) and Copper Catalysis for the Modular Cross-Coupling-Type Functionalization of Alkyl Iodides | ACS Catalysis |
| 114 | A strategy for ortho-phenylenediamine synthesis via dearomative-rearomative coupling of nitrobenzenes and amines | Chem |
| 115 | Charge-controlled Pd catalysis enables the meta-C–H activation and olefination of arenes | Chem |
| 116 | Ligand cooperativity enables highly enantioselective C–C σ-bond hydroboration of cyclopropanes | Chem |
| 117 | Multicomponent synthesis of α-chloro alkylboronic esters via visible-light-mediated dual catalysis | Chem |
| 118 | Organic charge-transfer complex induces chemoselective decarboxylation to aryl radicals for general functionalization | Chem |
| 119 | Three-component enantioselective alkenylation of organophosphonates via nickel metallaphotoredox catalysis | Chem |
| 120 | Visible-light-induced coupling of carboxylic acids with alcohols/amines via a phosphorous linchpin strategy | Chem |
| 121 | Ortho-Selective amination of arene carboxylic acids via rearrangement of acyl O-hydroxylamines | Chem. Sci. |
| 122 | Base-mediated homologative rearrangement of nitrogen–oxygen bonds of N-methyl-N-oxyamides | Chem. Sci. |
| 123 | Catalytic olefin metathesis in blood | Chem. Sci. |
| 124 | Direct conversion of amino acids to oxetanol bioisosteres via photoredox catalysis | Chem. Sci. |
| 125 | General acid-mediated aminolactone formation using unactivated alkenes | Chem. Sci. |
| 126 | Photocyclization by a triplet–triplet annihilation upconversion pair in water – avoiding UV-light and oxygen removal | Chem. Sci. |
| 127 | Reversible C–H bond silylation with a neutral silicon Lewis acid | Chem. Sci. |
| 128 | 1,2-Redox Transpositions of Tertiary Amides | JACS |
| 129 | O-Allylhydroxyamine: A Bifunctional Olefin for Construction of Axially and Centrally Chiral Amino Alcohols via Asymmetric Carboamidation | JACS |
| 130 | Z-Trisubstituted α,β-Unsaturated Esters and Acid Fluorides through Stereocontrolled Catalytic Cross-Metathesis | JACS |
| 131 | cis-Selective Hydrogenation of Aryl Germanes: A Direct Approach to Access Saturated Carbo- and Heterocyclic Germanes | JACS |
| 132 | ortho-Selective Dearomative [2π + 2σ] Photocycloadditions of Bicyclic Aza-Arenes | JACS |
| 133 | A Catalytic Asymmetric Hydrolactonization | JACS |
| 134 | A Convergent Total Synthesis of (+)-Ineleganolide | JACS |
| 135 | A Data-Driven Workflow for Assigning and Predicting Generality in Asymmetric Catalysis | JACS |
| 136 | A Formal γ-C–H Functionalization of Carboxylic Acids Guided by Metal-Nitrenoids as an Unprecedented Mechanistic Motif | JACS |
| 137 | A General Copper Catalytic System for Suzuki–Miyaura Cross-Coupling of Unactivated Secondary and Primary Alkyl Halides with Arylborons | JACS |
| 138 | A General Photocatalytic Strategy for Nucleophilic Amination of Primary and Secondary Benzylic C–H Bonds | JACS |
| 139 | A General and Modular Approach to BCP Alkylamines via Multicomponent Difunctionalization of [1.1.1]Propellane | JACS |
| 140 | A Machine Learning Approach to Model Interaction Effects: Development and Application to Alcohol Deoxyfluorination | JACS |
| 141 | A Metal-Free Cyclobutadiene Reagent for Intermolecular [4 + 2] Cycloadditions | JACS |
| 142 | A Photochemical Strategy for the Conversion of Nitroarenes into Rigidified Pyrrolidine Analogues | JACS |
| 143 | A Shapeshifting Roadmap for Polycyclic Skeletal Evolution | JACS |
| 144 | Alkane Solvent-Derived Acylation Reaction Driven by Electric Fields | JACS |
| 145 | Alkyl Radical Generation from Alkylboronic Pinacol Esters through Substitution with Aminyl Radicals | JACS |
| 146 | Allyl Alcohol as an Acrolein Equivalent in Enantioselective C–C Coupling: Total Synthesis of Amphidinolides R, J, and S | JACS |
| 147 | Anaerobic Hydroxylation of C(sp3)–H Bonds Enabled by the Synergistic Nature of Photoexcited Nitroarenes | JACS |
| 148 | Analyzing the Reaction of Orotidine 5′-Phosphate Decarboxylase as a Way to Examine Some Key Catalytic Proposals | JACS |
| 149 | Asymmetric anti-Selective Borylalkylation of Terminal Alkynes by Nickel Catalysis | JACS |
| 150 | Asymmetric Carbohydroxylation of Alkenes Using Photoenzymatic Catalysis | JACS |
| 151 | Asymmetric Catalytic Friedel–Crafts Reactions of Unactivated Arenes | JACS |
| 152 | Asymmetric Total Synthesis of Illisimonin A | JACS |
| 153 | Atom Transfer Radical Coupling Enables Highly Enantioselective Carbo-Oxygenation of Alkenes with Hydrocarbons | JACS |
| 154 | Azetidines with All-Carbon Quaternary Centers: Merging Relay Catalysis with Strain Release Functionalization | JACS |
| 155 | Azolation of Benzylic C–H Bonds via Photoredox-Catalyzed Carbocation Generation | JACS |
| 156 | Bicyclopentylation of Alcohols with Thianthrenium Reagents | JACS |
| 157 | Borane-Catalyzed C–F Bond Functionalization of gem-Difluorocyclopropenes Enables the Synthesis of Orphaned Cyclopropanes | JACS |
| 158 | Branched-Selective Cross-Electrophile Coupling of 2-Alkyl Aziridines and (Hetero)aryl Iodides Using Ti/Ni Catalysis | JACS |
| 159 | Breaking the tert-Butyllithium Contact Ion Pair: A Gateway to Alternate Selectivity in Lithiation Reactions | JACS |
| 160 | C(sp2)–H Hydroxylation via Catalytic 1,4-Ni Migration with N2O | JACS |
| 161 | Carbon Dioxide Radical Anion by Photoinduced Equilibration between Formate Salts and [11C, 13C, 14C]CO2: Application to Carbon Isotope Radiolabeling | JACS |
| 162 | Catalyst-Free Decarboxylative Amination of Carboxylic Acids in Water Microdroplets | JACS |
| 163 | Catalyst-Substrate Helical Character Matching Determines the Enantioselectivity in the Ishihara-Type Iodoarenes Catalyzed Asymmetric Kita-Dearomative Spirolactonization | JACS |
| 164 | Catalytic Asymmetric Cyclopropanations with Nonstabilized Carbenes | JACS |
| 165 | Catalytic Asymmetric Deoxygenative Cyclopropanation Reactions by a Chiral Salen-Mo Catalyst | JACS |
| 166 | Catalytic Asymmetric Hydrogen Atom Transfer: Enantioselective Hydroamination of Alkenes | JACS |
| 167 | Catalytic Asymmetric Oxidation of Amines to Hydroxylamines | JACS |
| 168 | Catalytic Cross-Metathesis Reactions That Afford E- and Z-Trisubstituted Alkenyl Bromides: Scope, Applications, and Mechanistic Insights | JACS |
| 169 | Catalytic Dehydrogenative (3 + 2) Cycloaddition of Alkylbenzenes via π-Coordination | JACS |
| 170 | Catalytic Enantioselective Intramolecular Oxa-Michael Reaction to α,β-Unsaturated Esters and Amides | JACS |
| 171 | Catalytic Enantioselective Nucleophilic Addition to Arynes by a New Quaternary Guanidinium Salt-Based Phase-Transfer Catalyst | JACS |
| 172 | Catalytic, Z-Selective, Semi-Hydrogenation of Alkynes with a Zinc–Anilide Complex | JACS |
| 173 | Catalytic, Asymmetric Michael-Aldol Annulations via a Stereodivergent/Stereoconvergent Path Operating under Curtin–Hammett Control | JACS |
| 174 | Catalytically Generated Meerwein’s Salt-Type Oxonium Ions for Friedel–Crafts C(sp2)–H Methylation with Methanol | JACS |
| 175 | Charting the Evolution of Chemoenzymatic Strategies in the Syntheses of Complex Natural Products | JACS |
| 176 | Chiral Amplification through the Interplay of Racemizing Conditions and Asymmetric Crystal Growth | JACS |
| 177 | Comprehensive Mechanistic Scenario for the Cu-Mediated Asymmetric Propargylic Sulfonylation Forging Tertiary Carbon Stereocenters | JACS |
| 178 | Controllable C–H Alkylation of Polyethers via Iron Photocatalysis | JACS |
| 179 | Convergent Deboronative and Decarboxylative Phosphonylation Enabled by the Phosphite Radical Trap “BecaP” | JACS |
| 180 | Copper and Silver Catalysis in the (3 + 2) Cycloaddition of Neutral Three-Atom Components with Terminal Alkynes | JACS |
| 181 | Copper-Catalyzed Asymmetric Functionalization of Vinyl Radicals for the Access to Vinylarene Atropisomers | JACS |
| 182 | Copper-Catalyzed Enantioselective Aerobic Alkene Aminooxygenation and Dioxygenation: Access to 2-Formyl Saturated Heterocycles and Unnatural Proline Derivatives | JACS |
| 183 | Copper-Mediated Dehydrogenative C(sp3)–H Borylation of Alkanes | JACS |
| 184 | Cr-Catalyzed Asymmetric Cross Aza-Pinacol Couplings for β-Amino Alcohol Synthesis | JACS |
| 185 | Cross-Coupling of Amines via Photocatalytic Denitrogenation of In Situ Generated Diazenes | JACS |
| 186 | Cyclobutenylidene: A Multifaceted Two-Coordinate Carbon Species Obtained via Skeletal Editing of a Cyclopropenylidene | JACS |
| 187 | C–H Functionalization of Pyridines via Oxazino Pyridine Intermediates: Switching to para-Selectivity under Acidic Conditions | JACS |
| 188 | C–N Bond Formation at Discrete CuIII–Aryl Complexes | JACS |
| 189 | Data Science-Enabled Palladium-Catalyzed Enantioselective Aryl-Carbonylation of Sulfonimidamides | JACS |
| 190 | Data-Driven Multi-Objective Optimization Tactics for Catalytic Asymmetric Reactions Using Bisphosphine Ligands | JACS |
| 191 | Derivatized Benzothiazoles as Two-Photon-Absorbing Organic Photosensitizers Active under Near Infrared Light Irradiation | JACS |
| 192 | Designing New Magnesium Pincer Complexes for Catalytic Hydrogenation of Imines and N-Heteroarenes: H2 and N–H Activation by Metal–Ligand Cooperation as Key Steps | JACS |
| 193 | Desymmetrization of Vicinal Bis(boronic) Esters by Enantioselective Suzuki–Miyaura Cross-Coupling Reaction | JACS |
| 194 | Development of a Nickel-Catalyzed N–N Coupling for the Synthesis of Hydrazides | JACS |
| 195 | Direct Deaminative Functionalization | JACS |
| 196 | Direct Dynamics Trajectories Demonstrate Dynamic Matching and Nonstatistical Radical Pair Intermediates during Fe-Oxo-Mediated C–H Functionalization Reactions | JACS |
| 197 | Directed Photochemically Mediated Nickel-Catalyzed (Hetero)arylation of Aliphatic C–H Bonds | JACS |
| 198 | Directing Group Repositioning Strategy Enabled Site- and Enantioselective Addition of Heteroaromatic C–H Bonds to Acyclic Internal Alkenes | JACS |
| 199 | Directional Ionic Bonds | JACS |
| 200 | Discovery of Biologically Optimized Polymyxin Derivatives Facilitated by Peptide Scanning and In Situ Screening Chemistry | JACS |
| 201 | Divergent Catalysis: Catalytic Asymmetric [4+2] Cycloaddition of Palladium Enolates | JACS |
| 202 | Divergent Synthetic Approach to Grayanane Diterpenoids | JACS |
| 203 | Divergent Total Synthesis and Characterization of Maxamycins | JACS |
| 204 | Domino Sequences Involving Stereoselective Hydrazone-Type Heck Reaction and Denitrogenative [1,5]-Sigmatropic Rearrangement | JACS |
| 205 | Dual Ruthenium-Catalyzed Alkene Isomerization–Hydrogen Auto-Transfer Unlocks Skipped Dienes as Pronucleophiles for Enantioselective Alcohol C–H Allylation | JACS |
| 206 | Dual-Hydrogen-Bond Donor and Brønsted Acid Cocatalysis Enables Highly Enantioselective Protio-Semipinacol Rearrangement Reactions | JACS |
| 207 | Dual-Ligand Catalyst for the Nondirected C–H Olefination of Heteroarenes | JACS |
| 208 | Dynamic Kinetic Reductive Conjugate Addition for Construction of Axial Chirality Enabled by Synergistic Photoredox/Cobalt Catalysis | JACS |
| 209 | Efficient Synthesis of α-Haloboronic Esters via Cu-Catalyzed Atom Transfer Radical Addition | JACS |
| 210 | Electrochemically Driven Deoxygenative Borylation of Alcohols and Carbonyl Compounds | JACS |
| 211 | Enantio- and Diastereoenriched Enzymatic Synthesis of 1,2,3-Polysubstituted Cyclopropanes from (Z/E)-Trisubstituted Enol Acetates | JACS |
| 212 | Enantio- and Diastereoselective De Novo Synthesis of 3-Substituted Proline Derivatives via Cooperative Photoredox/Brønsted Acid Catalysis and Epimerization | JACS |
| 213 | Enantioselective anti-Dihalogenation of Electron-Deficient Olefin: A Triplet Halo-Radical Pylon Intermediate | JACS |
| 214 | Enantioselective Amino- and Oxycyanation of Alkenes via Organic Photoredox and Copper Catalysis | JACS |
| 215 | Enantioselective C(sp3)–C(sp3) Reductive Cross-Electrophile Coupling of Unactivated Alkyl Halides with α-Chloroboronates via Dual Nickel/Photoredox Catalysis | JACS |
| 216 | Enantioselective C(sp3)–H Functionalization of Oxacycles via Photo-HAT/Nickel Dual Catalysis | JACS |
| 217 | Enantioselective Copper-Catalyzed Fukuyama Indole Synthesis from 2-Vinylphenyl Isocyanides | JACS |
| 218 | Enantioselective Dearomatization of Indoles via SmI2-Mediated Intermolecular Reductive Coupling with Ketones | JACS |
| 219 | Enantioselective Single and Dual α-C–H Bond Functionalization of Cyclic Amines via Enzymatic Carbene Transfer | JACS |
| 220 | Enantioselective Syntheses of Wickerols A and B | JACS |
| 221 | Enantioselective Synthesis of 1-Aminoindanes via [3 + 2] Annulation of Aldimines with Alkenes by Scandium-Catalyzed C–H Activation | JACS |
| 222 | Enantioselective Synthesis of α-Aminoboronic Acid Derivatives via Copper-Catalyzed N-Alkylation | JACS |
| 223 | Enantioselective Total Synthesis of (+)-KB343 | JACS |
| 224 | Enantioselective Total Synthesis of (+)-Pedrolide | JACS |
| 225 | Enantioselective Total Synthesis of (+)-Stephadiamine | JACS |
| 226 | Enantioselective Total Synthesis of (−)-Himalensine A via a Palladium and 4-Hydroxyproline Co-catalyzed Desymmetrization of Vinyl-bromide-tethered Cyclohexanones | JACS |
| 227 | Enhanced Excited-State Hydricity of Pd–H Allows for Unusual Head-to-Tail Hydroalkenylation of Alkenes | JACS |
| 228 | Exceptionally Long Lifetimes of Strongly Entangled Acyl–Trityl Radical Pairs Photochemically Generated in Crystalline Trityl Ketones | JACS |
| 229 | Expedient Access to Underexplored Chemical Space: Deoxygenative C(sp3)–C(sp3) Cross-Coupling | JACS |
| 230 | Exploring Cuneanes as Potential Benzene Isosteres and Energetic Materials: Scope and Mechanistic Investigations into Regioselective Rearrangements from Cubanes | JACS |
| 231 | Exploring the Limits of Intramolecular London Dispersion Stabilization with Bulky Dispersion Energy Donors in Alkane Solution | JACS |
| 232 | Formal Cross-Coupling of Amines and Carboxylic Acids to Form sp3–sp2 Carbon–Carbon Bonds | JACS |
| 233 | Formation of C(sp2)–C(sp3) Bonds Instead of Amide C–N Bonds from Carboxylic Acid and Amine Substrate Pools by Decarbonylative Cross-Electrophile Coupling | JACS |
| 234 | Formation of Isolable Dearomatized [4 + 2] Cycloadducts from Benzenes, Naphthalenes, and N-Heterocycles Using 1,2-Dihydro-1,2,4,5-tetrazine-3,6-diones as Arenophiles under Visible Light Irradiation | JACS |
| 235 | From the Glovebox to the Benchtop: Air-Stable High Performance Molybdenum Alkylidyne Catalysts for Alkyne Metathesis | JACS |
| 236 | Generating Fischer-Type Rh-Carbenes with Rh-Carbynoids | JACS |
| 237 | Halide Noninnocence and Direct Photoreduction of Ni(II) Enables Coupling of Aryl Chlorides in Dual Catalytic, Carbon–Heteroatom Bond-Forming Reactions | JACS |
| 238 | Hydrotrifluoroacetylation of Alkenes via Designer Masked Acyl Reagents | JACS |
| 239 | Identification of Alkoxy Radicals as Hydrogen Atom Transfer Agents in Ce-Catalyzed C–H Functionalization | JACS |
| 240 | Indolo[2,3-b]quinoxaline as a Low Reduction Potential and High Stability Anolyte Scaffold for Nonaqueous Redox Flow Batteries | JACS |
| 241 | Intermolecular Organophotocatalytic Cyclopropanation of Unactivated Olefins | JACS |
| 242 | Interrogating the Mechanistic Features of Ni(I)-Mediated Aryl Iodide Oxidative Addition Using Electroanalytical and Statistical Modeling Techniques | JACS |
| 243 | Intramolecular Rhodium-Catalyzed [(3+2+2)] Carbocyclization Reactions with Dienylidenecyclopropanes: A Concise and Stereoselective Total Synthesis of the Sesquiterpene (+)-Zizaene | JACS |
| 244 | Iridium-Catalyzed Asymmetric Difunctionalization of C–C σ-Bonds Enabled by Ring-Strained Boronate Complexes | JACS |
| 245 | Iridium-Catalyzed Enantioconvergent Borrowing Hydrogen Annulation of Racemic 1,4-Diols with Amines | JACS |
| 246 | Iridium-Catalyzed, Site-Selective Silylation of Secondary C(sp3)–H Bonds in Secondary Alcohols and Ketones | JACS |
| 247 | Iron-Catalyzed C(Sp3)–H Borylation, Thiolation, and Sulfinylation Enabled by Photoinduced Ligand-to-Metal Charge Transfer | JACS |
| 248 | Iron-Mediated Photochemical Anti-Markovnikov Hydroazidation of Unactivated Olefins | JACS |
| 249 | Isotopic Fractionation as a Mechanistic Probe in Light-Driven C–H Bond Exchange Reactions | JACS |
| 250 | Late-Stage C(sp3)–H Methylation of Drug Molecules | JACS |
| 251 | Late-Stage Chemo- and Enantioselective Oxidation of Indoles to C3-Monosubstituted Oxindoles | JACS |
| 252 | Late-Stage Molecular Editing Enabled by Ketone Chain-Walking Isomerization | JACS |
| 253 | Ligand Control in Co-Catalyzed Regio- and Enantioselective Hydroboration: Homoallyl Secondary Boronates via Uncommon 4,3-Hydroboration of 1,3-Dienes | JACS |
| 254 | Ligand-Enabled γ-C(sp3)–H Hydroxylation of Free Amines with Aqueous Hydrogen Peroxide | JACS |
| 255 | Mechanism-Guided Design of Robust Palladium Catalysts for Selective Aerobic Oxidation of Polyols | JACS |
| 256 | Mechanistic Investigation of Ni-Catalyzed Reductive Cross-Coupling of Alkenyl and Benzyl Electrophiles | JACS |
| 257 | Mechanochemistry-Directed Ligand Design: Development of a High-Performance Phosphine Ligand for Palladium-Catalyzed Mechanochemical Organoboron Cross-Coupling | JACS |
| 258 | Merging of Light/Dark Palladium Catalytic Cycles Enables Multicomponent Tandem Alkyl Heck/Tsuji–Trost Homologative Amination Reaction toward Allylic Amines | JACS |
| 259 | Modular Access tometa-Substituted Benzenes via Mo-Catalyzed Intermolecular Deoxygenative Benzene Formation | JACS |
| 260 | Modular Diazo Compound for the Bioreversible Late-Stage Modification of Proteins | JACS |
| 261 | Modular Synthesis of Unnatural Peptides via Rh(III)-Catalyzed Diastereoselective Three-Component Carboamidation Reaction | JACS |
| 262 | Ni-Electrocatalytic Enantioselective Doubly Decarboxylative C(sp3)–C(sp3) Cross Coupling | JACS |
| 263 | Nickel Meets Aryl Thianthrenium Salts: Ni(I)-Catalyzed Halogenation of Arenes | JACS |
| 264 | Nickel-Catalyzed Enantioselective Electrochemical Reductive Cross-Coupling of Aryl Aziridines with Alkenyl Bromides | JACS |
| 265 | Nickel-Catalyzed Enantioselective Reductive Arylation and Heteroarylation of Aldimines via an Elementary 1,4-Addition | JACS |
| 266 | Nickel-Catalyzed Exhaustive Hydrodefluorination of Perfluoroalkyl Arenes | JACS |
| 267 | Nickel-Catalyzed Reductive [4 + 1] Sila-Cycloaddition of 1,3-Dienes with Dichlorosilanes | JACS |
| 268 | One-Bond-Nucleophilicity and -Electrophilicity Parameters: An Efficient Ordering System for 1,3-Dipolar Cycloadditions | JACS |
| 269 | One-Pot Chemoenzymatic Cascade for the Enantioselective C(1)-Allylation of Tetrahydroisoquinolines | JACS |
| 270 | One-Pot Synthesis of Sulfonamides from Unactivated Acids and Amines via Aromatic Decarboxylative Halosulfonylation | JACS |
| 271 | Orange Light-Driven C(sp2)–C(sp3) Cross-Coupling via Spin-Forbidden Ir(III) Metallaphotoredox Catalysis | JACS |
| 272 | Oxetane Synthesis via Alcohol C–H Functionalization | JACS |
| 273 | Oxidative Addition of Aryl Electrophiles into a Red-Light-Active Bismuthinidene | JACS |
| 274 | Oxidative Cross Dehydrogenative Coupling of N-Heterocycles with Aldehydes through C(sp3)–H Functionalization | JACS |
| 275 | Palladium and Iron Cocatalyzed Aerobic Alkene Aminoboration | JACS |
| 276 | Palladium-Catalyzed Stitching of 1,3-C(sp3)–H Bonds with Dihaloarenes: Short Synthesis of (±)-Echinolactone D | JACS |
| 277 | Palladium-Catalyzed Trans-Selective Synthesis of Spirocyclic Cyclobutanes Using α,α-Dialkylcrotyl- and Allylhydrazones | JACS |
| 278 | Pd(0)-Catalyzed Asymmetric 7-Endo Hydroacyloxylative Cyclization of 1,6-Enyne Enabled by an Anion Ligand-Directed Strategy | JACS |
| 279 | Pd-Catalyzed Amination of Base-Sensitive Five-Membered Heteroaryl Halides with Aliphatic Amines | JACS |
| 280 | Photo- and Metal-Mediated Deconstructive Approaches to Cyclic Aliphatic Amine Diversification | JACS |
| 281 | Photocatalytic 1,2-Phosphorus-Migrative [3 + 2] Cycloaddition of Tri(t-butyl)phosphine with Terminal Alkynes | JACS |
| 282 | Photocatalytic Anti-Markovnikov Hydroamination of Alkenes with Primary Heteroaryl Amines | JACS |
| 283 | Photochemical Organocatalytic Functionalization of Pyridines via Pyridinyl Radicals | JACS |
| 284 | Photoinduced Copper-Catalyzed Late-Stage Azidoarylation of Alkenes via Arylthianthrenium Salts | JACS |
| 285 | Photoinduced Halogen-Atom Transfer by N-Heterocyclic Carbene-Ligated Boryl Radicals for C(sp3)–C(sp3) Bond Formation | JACS |
| 286 | Photoinduced Nickel-Catalyzed Selective N-Demethylation of Trialkylamines Using C(sp2)–Bromides as HAT Reagents | JACS |
| 287 | Photoredox Catalysis-Enabled Sulfination of Alcohols and Bromides | JACS |
| 288 | Photoredox Cleavage of a Csp3–Csp3 Bond in Aromatic Hydrocarbons | JACS |
| 289 | Photoredox-Nickel Dual-Catalyzed C-Alkylation of Secondary Nitroalkanes: Access to Sterically Hindered α-Tertiary Amines | JACS |
| 290 | Photosensitized [2 + 2]-Cycloadditions of Dioxaborole: Reactivity Enabled by Boron Ring Constraint Strategy | JACS |
| 291 | Physical Separation of Enantiomeric Products by Compartmentalized Parallel Kinetic Resolution | JACS |
| 292 | Polar Heterobenzylic C(sp3)–H Chlorination Pathway Enabling Efficient Diversification of Aromatic Nitrogen Heterocycles | JACS |
| 293 | Polarity Transduction Enables the Formal Electronically Mismatched Radical Addition to Alkenes | JACS |
| 294 | Protodemetalation of (Bipyridyl)Ni(II)–Aryl Complexes Shows Evidence for Five-, Six-, and Seven-Membered Cyclic Pathways | JACS |
| 295 | Radical Hydrocarboxylation of Unactivated Alkenes via Photocatalytic Formate Activation | JACS |
| 296 | Rapid Access to 2-Substituted Bicyclo[1.1.1]pentanes | JACS |
| 297 | Rapid and Modular Access to Quaternary Carbons from Tertiary Alcohols via Bimolecular Homolytic Substitution | JACS |
| 298 | Redox-Paired Alkene Difunctionalization Enables Skeletally Divergent Synthesis | JACS |
| 299 | Reductive Aza-Pauson-Khand Reaction of Nitriles | JACS |
| 300 | Reductive Cross-Coupling of Olefins via a Radical Pathway | JACS |
| 301 | Regiospecific Alkene Aminofunctionalization via an Electrogenerated Dielectrophile | JACS |
| 302 | Remote Hydroamination of Disubstituted Alkenes by a Combination of Isomerization and Regioselective N–H Addition | JACS |
| 303 | Role of Noncovalent Interactions in Inducing High Enantioselectivity in an Alcohol Reductive Deoxygenation Reaction Involving a Planar Carbocationic Intermediate | JACS |
| 304 | Room-Temperature Copper-Mediated Radiocyanation of Aryldiazonium Salts and Aryl Iodides via Aryl Radical Intermediates | JACS |
| 305 | Room-Temperature Cu-Catalyzed Amination of Aryl Bromides Enabled by DFT-Guided Ligand Design | JACS |
| 306 | Selective P450BM3 Hydroxylation of Cyclobutylamine and Bicyclo[1.1.1]pentylamine Derivatives: Underpinning Synthetic Chemistry for Drug Discovery | JACS |
| 307 | Sigma-Bond Metathesis as an Unusual Asymmetric Induction Step in Rhodium-Catalyzed Enantiodivergent Synthesis of C–N Axially Chiral Biaryls | JACS |
| 308 | Silica Supported Organometallic IrI Complexes Enable Efficient Catalytic Methane Borylation | JACS |
| 309 | Silver(I)-Catalyzed Synthesis of Cuneanes from Cubanes and their Investigation as Isosteres | JACS |
| 310 | Site- and Stereoselective Synthesis of Alkenyl Chlorides by Dual Functionalization of Internal Alkynes via Photoredox/Nickel Catalysis | JACS |
| 311 | Skeletal Editing Approach to Bridge-Functionalized Bicyclo[1.1.1]pentanes from Azabicyclo[2.1.1]hexanes | JACS |
| 312 | Skeletal Editing of Pyrimidines to Pyrazoles by Formal Carbon Deletion | JACS |
| 313 | Skeletal Transformation of Unactivated Arenes Enabled by a Low-Temperature Dearomative (3 + 2) Cycloaddition | JACS |
| 314 | Small DNAs That Specifically and Tightly Bind Transition Metal Ions | JACS |
| 315 | Stereocontrolled Radical Thiophosphorylation | JACS |
| 316 | Stereoselective Synthesis of Trisubstituted Alkenes via Copper Hydride-Catalyzed Alkyne Hydroalkylation | JACS |
| 317 | Stereospecific Acylative Suzuki–Miyaura Cross-Coupling: General Access to Optically Active α-Aryl Carbonyl Compounds | JACS |
| 318 | Strategies for Nucleophilic C(sp3)–(Radio)Fluorination | JACS |
| 319 | Substrate Plasticity Enables Group-Selective Transmetalation: Catalytic Stereospecific Cross-Couplings of Tertiary Boronic Esters | JACS |
| 320 | Substrate-Directed Enantioselective Aziridination of Alkenyl Alcohols Controlled by a Chiral Cation | JACS |
| 321 | Supramolecular Capsule-Catalyzed Highly β-Selective Furanosylation Independent of the SN1/SN2 Reaction Pathway | JACS |
| 322 | Synthesis and Characterization of Donor–Acceptor Iron Porphyrin Carbenes and Their Reactivities in N–H Insertion and Related Three-Component Reaction | JACS |
| 323 | Synthesis of 1,3-Dienes via Ligand-Enabled Sequential Dehydrogenation of Aliphatic Acids | JACS |
| 324 | Synthesis of Chlorinated Oligopeptides via γ- and δ-Selective Hydrogen Atom Transfer Enabled by the N-Chloropeptide Strategy | JACS |
| 325 | Synthesis of Phosphet-2-one Derivatives via Phosphinidene Transfer to Cyclopropenones | JACS |
| 326 | Synthesis of a C2-Symmetric Chiral Borinic Acid and Its Application in Catalytic Desymmetrization of 2,2-Disubstituted-1,3-Propanediols | JACS |
| 327 | Synthesis of γ-Lactams from Acrylamides by Single-Carbon Atom Doping Annulation | JACS |
| 328 | Tandem C/N-Difunctionalization of Nitroarenes: Reductive Amination and Annulation by a Ring Expansion/Contraction Sequence | JACS |
| 329 | Tandem Dearomatization/Enantioselective Allylic Alkylation of Pyridines | JACS |
| 330 | Ti-Catalyzed Modular Ketone Synthesis from Carboxylic Derivatives and gem-Dihaloalkanes | JACS |
| 331 | Total Syntheses of Scabrolide A and Yonarolide | JACS |
| 332 | Total Synthesis of (+)-Euphorikanin A via an Atropospecific Cascade | JACS |
| 333 | Total Synthesis of Strempeliopidine and Non-Natural Stereoisomers through a Convergent Petasis Borono–Mannich Reaction | JACS |
| 334 | Total Synthesis of Vilmoraconitine | JACS |
| 335 | Tris(bicyclo[1.1.1]pentyl)phosphine: An Exceptionally Small Tri-tert-alkylphosphine and Its Bis-Ligated Pd(0) Complex | JACS |
| 336 | Ultrahigh-Throughput Directed Evolution of a Metal-Free α/β-Hydrolase with a Cys-His-Asp Triad into an Efficient Phosphotriesterase | JACS |
| 337 | Unlocking the Potential of β-Fragmentation of Aminophosphoranyl Radicals for Sulfonyl Radical Reactions | JACS |
| 338 | Using Data Science for Mechanistic Insights and Selectivity Predictions in a Non-Natural Biocatalytic Reaction | JACS |
| 339 | Zirconium-Catalyzed C–H Alumination of Polyolefins, Paraffins, and Methane | JACS |
| 340 | β-Boron Effect Enables Regioselective and Stereospecific Electrophilic Addition to Alkenes | JACS |
| 341 | μMap Photoproximity Labeling Enables Small Molecule Binding Site Mapping | JACS |
| 342 | Acetyl-Click Screening Platform Identifies Small-Molecule Inhibitors of Histone Acetyltransferase 1 (HAT1) | JMC |
| 343 | Conformationally Restricted σ1 Receptor Antagonists from (−)-Isopulegol | JMC |
| 344 | Discovery of a Series of Potent, Selective, and Orally Bioavailable Nucleoside Inhibitors of CD73 That Demonstrates In Vivo Antitumor Activity | JMC |
| 345 | Macrocycles in Drug Discovery─Learning from the Past for the Future | JMC |
| 346 | Oxetanes in Drug Discovery Campaigns | JMC |
| 347 | The Role of Allylic Strain for Conformational Control in Medicinal Chemistry | JMC |
| 348 | Arene C–H Amination with N-Heteroarenes by Catalytic DDQ Photocatalysis | JOC |
| 349 | Electrochemical Phenyl–Carbonyl Coupling Reaction of Aromatic Aldehydes or Ketones | JOC |
| 350 | Electroreductive Nickel-Catalyzed Allylation of Aryl Chlorides | JOC |
| 351 | No-Deuterium Proton (No-D) NMR as a Convenient Method for Analysis of Organic Solvents | JOC |
| 352 | Rapid Lewis Acid Screening and Reaction Optimization Using 3D-Printed Catalyst-Impregnated Stirrer Devices in the Synthesis of Heterocycles | JOC |
| 353 | Synthesis of Isoquinolines and Related Heterocycles under Visible-Light Conditions | JOC |
| 354 | 2-Oxabicyclo[2.1.1]hexanes as saturated bioisosteres of the ortho-substituted phenyl ring | Nat. Chem. |
| 355 | A catalytic alkene insertion approach to bicyclo[2.1.1]hexane bioisosteres | Nat. Chem. |
| 356 | A general arene C–H functionalization strategy via electron donor–acceptor complex photoactivation | Nat. Chem. |
| 357 | Alkyl sulfinates as cross-coupling partners for programmable and stereospecific installation of C(sp3) bioisosteres | Nat. Chem. |
| 358 | Arenes participate in 1,3-dipolar cycloaddition with in situ-generated diazoalkenes | Nat. Chem. |
| 359 | Bismuth radical catalysis in the activation and coupling of redox-active electrophiles | Nat. Chem. |
| 360 | Capturing primary ozonides for a syn-dihydroxylation of olefins | Nat. Chem. |
| 361 | Carbonyl cross-metathesis via deoxygenative gem-di-metal catalysis | Nat. Chem. |
| 362 | Catalytic enantioselective nucleophilic desymmetrization of phosphonate esters | Nat. Chem. |
| 363 | Catalytic undirected borylation of tertiary C–H bonds in bicyclo[1.1.1]pentanes and bicyclo[2.1.1]hexanes | Nat. Chem. |
| 364 | Cu-catalysed enantioselective radical heteroatomic S–O cross-coupling | Nat. Chem. |
| 365 | Enabling late-stage drug diversification by high-throughput experimentation with geometric deep learning | Nat. Chem. |
| 366 | Enantioselective synthesis of atropisomeric indoles via iron-catalysed oxidative cross-coupling | Nat. Chem. |
| 367 | Energy-transfer-induced [3+2] cycloadditions of N–N pyridinium ylides | Nat. Chem. |
| 368 | Iterative synthesis of 1,3-polyboronic esters with high stereocontrol and application to the synthesis of bahamaolide A | Nat. Chem. |
| 369 | Metal-free reduction of CO2 to formate using a photochemical organohydride-catalyst recycling strategy | Nat. Chem. |
| 370 | Metalloradical approach for concurrent control in intermolecular radical allylic C−H amination | Nat. Chem. |
| 371 | Modular enantioselective access to β-amino amides by Brønsted acid-catalysed multicomponent reactions | Nat. Chem. |
| 372 | Multi-site programmable functionalization of alkenes via controllable alkene isomerization | Nat. Chem. |
| 373 | Organocatalytic asymmetric deoxygenation of sulfones to access chiral sulfinyl compounds | Nat. Chem. |
| 374 | Organogel delivery vehicles for the stabilization of organolithium reagents | Nat. Chem. |
| 375 | Photocatalytic hydrofluoroalkylation of alkenes with carboxylic acids | Nat. Chem. |
| 376 | Programmable late-stage functionalization of bridge-substituted bicyclo[1.1.1]pentane bis-boronates | Nat. Chem. |
| 377 | Stepwise on-demand functionalization of multihydrosilanes enabled by a hydrogen-atom-transfer photocatalyst based on eosin Y | Nat. Chem. |
| 378 | Using enzymes to tame nitrogen-centred radicals for enantioselective hydroamination | Nat. Chem. |
| 379 | meta-Selective C–H arylation of phenols via regiodiversion of electrophilic aromatic substitution | Nat. Chem. |
| 380 | A neural network model informs the total synthesis of clovane sesquiterpenoids | Nat. Synth. |
| 381 | Alkyne synthesis through coupling of gem-diborylalkanes with carboxylic acid esters | Nat. Synth. |
| 382 | Direct synthesis of unprotected aryl C-glycosides by photoredox Ni-catalysed cross-coupling | Nat. Synth. |
| 383 | Light-driven C–O coupling of carboxylic acids and alkyl halides over a Ni single-atom catalyst | Nat. Synth. |
| 384 | Multi-carbon labelling of active pharmaceutical ingredients enabled by a three-gas surrogate hydroformylation | Nat. Synth. |
| 385 | Synthesis of axially chiral alkenylboronates through combined copper- and palladium-catalysed atroposelective arylboration of alkynes | Nat. Synth. |
| 386 | A ligand insertion mechanism for cooperative NH3 capture in metal–organic frameworks | Nature |
| 387 | An electric molecular motor | Nature |
| 388 | Arenium-ion-catalysed halodealkylation of fully alkylated silanes | Nature |
| 389 | Carbon-to-nitrogen single-atom transmutation of azaarenes | Nature |
| 390 | Catalytic asymmetric synthesis of cannabinoids and menthol from neral | Nature |
| 391 | Complex molecule synthesis by electrocatalytic decarboxylative cross-coupling | Nature |
| 392 | Control of stereogenic oxygen in a helically chiral oxonium ion | Nature |
| 393 | Copper-catalysed enantioconvergent alkylation of oxygen nucleophiles | Nature |
| 394 | De novo design of modular peptide-binding proteins by superhelical matching | Nature |
| 395 | Electrochemical reactor dictates site selectivity in N-heteroarene carboxylations | Nature |
| 396 | Electrophotocatalytic oxygenation of multiple adjacent C–H bonds | Nature |
| 397 | Enantioconvergent Cu-catalysed N-alkylation of aliphatic amines | Nature |
| 398 | Enantioselective transition-metal catalysis via an anion-binding approach | Nature |
| 399 | Functional-group translocation of cyano groups by reversible C–H sampling | Nature |
| 400 | General access to cubanes as benzene bioisosteres | Nature |
| 401 | General cross-coupling reactions with adaptive dynamic homogeneous catalysis | Nature |
| 402 | Hydrogen-bond-acceptor ligands enable distal C(sp3)–H arylation of free alcohols | Nature |
| 403 | Organic reaction mechanism classification using machine learning | Nature |
| 404 | Photocatalytic phosphine-mediated water activation for radical hydrogenation | Nature |
| 405 | Regioselective aliphatic C–H functionalization using frustrated radical pairs | Nature |
| 406 | Selective methane oxidation by molecular iron catalysts in aqueous medium | Nature |
| 407 | Structure-based design of bitopic ligands for the µ-opioid receptor | Nature |
| 408 | Tracking chromatin state changes using nanoscale photo-proximity labelling | Nature |
| 409 | Transannular C–H functionalization of cycloalkane carboxylic acids | Nature |
| 410 | Easy Removal of Triphenylphosphine Oxide from Reaction Mixtures by Precipitation with CaBr2 | OPRD |
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| 412 | An Organocatalytic Oxy-Cope/Michael Cascade Reaction | Org. Lett. |
| 413 | Copper-Catalyzed Asymmetric Boroprotonation of Phosphinylallenes | Org. Lett. |
| 414 | Deoxyfluorination of Electron-Deficient Phenols | Org. Lett. |
| 415 | From Cycloalkanols to Heterocycles via Nitrogen Insertion | Org. Lett. |
| 416 | Inverse Electron Demand Diels–Alder-Type Heterocycle Syntheses with 1,2,3-Triazine 1-Oxides: Expanded Versatility | Org. Lett. |
| 417 | Radical C(sp3)–S Coupling for the Synthesis of α-Amino Sulfides | Org. Lett. |
| 418 | Regioselective Synthesis of Fully Substituted Fused Pyrroles through an Oxidant-Free Multicomponent Reaction | Org. Lett. |
| 419 | Stereoconvergent Direct Ring Expansion of Cyclopropyl Ketones to Cyclopentanones | Org. Lett. |
| 420 | Abiotic peptides as carriers of information for the encoding of small-molecule library synthesis | Science |
| 421 | Acceleration of Diels-Alder reactions by mechanical distortion | Science |
| 422 | Aminodealkenylation: Ozonolysis and copper catalysis convert C(sp 3 )–C(sp 2 ) bonds to C(sp 3 )–N bonds | Science |
| 423 | Aromatic nitrogen scanning by ipso -selective nitrene internalization | Science |
| 424 | Complex scaffold remodeling in plant triterpene biosynthesis | Science |
| 425 | Computer-aided key step generation in alkaloid total synthesis | Science |
| 426 | Dearomative ring expansion of thiophenes by bicyclobutane insertion | Science |
| 427 | Diberyllocene, a stable compound of Be(I) with a Be–Be bond | Science |
| 428 | Enantioselective electrochemical cobalt-catalyzed aryl C–H activation reactions | Science |
| 429 | Exploiting the Marcus inverted region for first-row transition metal–based photoredox catalysis | Science |
| 430 | Generality-oriented optimization of enantioselective aminoxyl radical catalysis | Science |
| 431 | Kinetic and thermodynamic control of C(sp 2 )–H activation enables site-selective borylation | Science |
| 432 | Mechanistic snapshots of rhodium-catalyzed acylnitrene transfer reactions | Science |
| 433 | Modification of ground-state chemical reactivity via light–matter coherence in infrared cavities | Science |
| 434 | Multiplicative enhancement of stereoenrichment by a single catalyst for deracemization of alcohols | Science |
| 435 | Overcoming the limitations of Kolbe coupling with waveform-controlled electrosynthesis | Science |
| 436 | Oxidative rearrangement of 1,1-disubstituted alkenes to ketones | Science |
| 437 | Regio-controllable [2+2] benzannulation with two adjacent C(sp 3 )–H bonds | Science |
| 438 | Rhodium catalyzed tunable amide homologation through a hook-and-slide strategy | Science |
| 439 | Single–carbon atom transfer to α,β-unsaturated amides from N-heterocyclic carbenes | Science |
| 440 | Stereoselective amino acid synthesis by synergistic photoredox-pyridoxal radical biocatalysis | Science |
| 441 | Taming secondary benzylic cations in catalytic asymmetric S N 1 reactions | Science |
| 442 | Tracking C–H activation with orbital resolution | Science |